This paper is concerned with the space of all compact adjoint operators from dual spaces of Banach spaces into dual spaces of Banach spaces and approximation properties. For some topology on the space of all bounded linear operators from separable dual spaces of Banach spaces into dual spaces of Banach spaces, it is shown that if a bounded linear operator is approximated by a net of compact adjoint operators, then the operator can be approximated by a sequence of compact adjoint operators whose operator norms are less than or equal to the operator norm of the operator. Also we obtain applications of the theory and, in particular, apply the theory to approximation properties.